Hi,
Effectively, UART2 and UART3 are available on extension board, if UART3 is remapped on PB6/PB7 pins of the STM32, but these pins are shared with I2C1.
So using UART3 and I2C1 are exclusive on extension board.
A solution may be to modify the Primer2 board by removing the IrDA chip, in order to get the UART1 pins (PA9/PA10 µC pins).
Yves